HRID49369

反应详情

EQUATION

反应方程式

REACTANTS

反应物

$结构：CC/C(=C\CO)c1csc(COc2ccc(CO[Si](C)(C)C(C)(C)C)c(CO[Si](C)(C)C(C)(C)C)c2)c1$

HCID69824522

未命名化合物

PRODUCTS

生成物

$结构：CC/C(=C\C=O)c1csc(COc2ccc(CO[Si](C)(C)C(C)(C)C)c(CO[Si](C)(C)C(C)(C)C)c2)c1$

HCID88011850

未命名化合物

收率 86%

AUXILIARIES

试剂、催化剂与溶剂

催化剂HCID178418406

未命名化合物

PROCEDURE

实验过程

In a manner similar to that of Example 7(c), by reaction of 2.1 g (3.7 mmol) of (E)-3-{5-[3,4-bis(tert-butyldimethylsilanyloxymethyl)phenoxymethyl]-3-thienyl}pent-2-en-1-ol with 4.9 g (56 mmol) of manganese dioxide, the crude product (1.8 g) is the expected aldehyde, obtained in a yield of 86%.

WORKUP

后处理

customobtained in a yield of 86%

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-069a0a62fd8b411bb0623307cb694731
来源数据集: uspto-grants-2004_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06706725B1
来源说明: uspto-grants-2004_03

反应 SMILES

[Si:1]([O:8][CH2:9][C:10]1[CH:11]=[C:12]([CH:26]=[CH:27][C:28]=1[CH2:29][O:30][Si:31]([C:34]([CH3:37])([CH3:36])[CH3:35])([CH3:33])[CH3:32])[O:13][CH2:14][C:15]1[S:19][CH:18]=[C:17](/[C:20](/[CH2:24][CH3:25])=[CH:21]/[CH2:22][OH:23])[CH:16]=1)([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2]>[O-2].[O-2].[Mn+4]>[Si:1]([O:8][CH2:9][C:10]1[CH:11]=[C:12]([CH:26]=[CH:27][C:28]=1[CH2:29][O:30][Si:31]([C:34]([CH3:35])([CH3:37])[CH3:36])([CH3:32])[CH3:33])[O:13][CH2:14][C:15]1[S:19][CH:18]=[C:17](/[C:20](/[CH2:24][CH3:25])=[CH:21]/[CH:22]=[O:23])[CH:16]=1)([C:4]([CH3:6])([CH3:5])[CH3:7])([CH3:3])[CH3:2]