HuagongsheHuagongshe Chemistry Print Report · For research reference only
(e)-3-{5-[3,4-Bis(tert-butyldimethylsilanyloxymethyl)phenoxymethyl]-3-thienyl}pent-2-en-1-ol → HCID 88011850, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (e)-3-{5-[3,4-Bis(tert-butyldimethylsilanyloxymethyl)phenoxymethyl]-3-thienyl}pent-2-en-1-ol | HCID 69824522 | — |
| Catalyst | HCID 178418406 | HCID 178418406 | — |
| Product | HCID 88011850 | HCID 88011850 | 86% |
Reaction Steps
In a manner similar to that of Example 7(c), by reaction of 2.1 g (3.7 mmol) of (E)-3-{5-[3,4-bis(tert-butyldimethylsilanyloxymethyl)phenoxymethyl]-3-thienyl}pent-2-en-1-ol with 4.9 g (56 mmol) of manganese dioxide, the crude product (1.8 g) is the expected aldehyde, obtained in a yield of 86%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06706725B1 |
| Source dataset | uspto-grants-2004_03 |
| ORD ID | ord-069a0a62fd8b411bb0623307cb694731 |
| Source note | uspto-grants-2004_03 |