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HRID495210

反应详情

EQUATION

反应方程式

HRID 495210 的结构方程式

REACTANTS

反应物

2
结构：CC(C)(C)O
HCID6386

tert-Butyl alcohol

C4H10O

结构：CCC(O)=C1C(=O)OC(C)(C)OC1=O
HCID54706177

5-(1-Hydroxypropylidene)-2,2-dimethyl-1,3-dioxane-4,6-dione

C9H12O5

PRODUCTS

生成物

1
结构：CCC(=O)CC(=O)OC(C)(C)C
HCID11182898

Tert-butyl 3-oxopentanoate

C9H16O3

AUXILIARIES

试剂、催化剂与溶剂

1
结构：c1ccccc1
溶剂HCID241

Benzene

C6H6

PROCEDURE

实验过程

A solution of 5-(1-hydroxypropylidene)-2,2 dimethyl-1,3-dioxane-4,6-dione (18.2 g, 69.4 mmol), tBuOH (19.9 ml, 208 mmol) and benzene (400 ml) was heated at reflux for 6 hours. Concentration in vacuo gave a red liquid.

WORKUP

后处理

  1. temperatureat reflux for 6 hours
  2. concentrationConcentration in vacuo
  3. customgave a red liquid