HuagongsheHuagongshe Chemistry Print Report · For research reference only
tert-Butanol → Tert-butyl 3-oxopentanoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | tert-Butanol | HCID 6386 | — |
| Reactant | 5-(1-Hydroxypropylidene)-2,2-dimethyl-1,3-dioxane-4,6-dione | HCID 54706177 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | Tert-butyl 3-oxopentanoate | HCID 11182898 | — |
Reaction Steps
A solution of 5-(1-hydroxypropylidene)-2,2 dimethyl-1,3-dioxane-4,6-dione (18.2 g, 69.4 mmol), tBuOH (19.9 ml, 208 mmol) and benzene (400 ml) was heated at reflux for 6 hours. Concentration in vacuo gave a red liquid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07538231B2 |
| Source dataset | uspto-grants-2009_05 |
| ORD ID | ord-6cc8a5517af54501b9a98e1722804619 |
| Source note | uspto-grants-2009_05 |