Cyclohexene → HCID 69796510, compound

HRID 495604Notes

Reaction equation

HRID 495604 reaction equation
C(OC([N:11]1[CH2:15][CH2:14][CH2:13][C@@H:12]1[CH2:16][O:17][Si:18]([C:21]([CH3:24])([CH3:23])[CH3:22])([CH3:20])[CH3:19])=O)C1C=CC=CC=1.C1CCCCC=1>C(O)C.[Pd]>[Si:18]([O:17][CH2:16][C@H:12]1[CH2:13][CH2:14][CH2:15][NH:11]1)([C:21]([CH3:24])([CH3:23])[CH3:22])([CH3:20])[CH3:19]

Participants

5

Reactant 2

HCID 8079CyclohexeneHCID 14629888HCID 14629888, compound

Product 1

HCID 69796510HCID 69796510, compoundYield 86.3%

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

To a solution of D2 (12.7 g, 0.036 mol) and cyclohexene (excess, 20 ml) in ethanol (100 ml) was added 10% palladium on charcoal catalyst. Reaction was heated at reflux overnight and cooled. Catalyst was filtered and the filtrate concentrated to leave an oil (6.69 g) which was used in the next step without purification.

Workup

  1. customReaction
  2. temperaturewas heated
  3. temperatureat reflux overnight
  4. temperaturecooled
  5. filtrationCatalyst was filtered
  6. concentrationthe filtrate concentrated

Sources & evidence

ORD record
ord-aa3eccba618748809eeaaf288611ce69
Source dataset
uspto-grants-2005_09
Patent number
US06939891B2

Reaction notes

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