Acetic Acid → HCID 15551922, compound

HRID 496789Notes

Reaction equation

HRID 496789 reaction equation
[CH3:1][S:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[C:9]1[CH:14]=[CH:13][C:12]([N+:15]([O-:17])=[O:16])=[CH:11][CH:10]=1.[OH2:18].C(O)(=[O:21])C>>[CH3:1][S:2]([C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[C:9]1[CH:14]=[CH:13][C:12]([N+:15]([O-:17])=[O:16])=[CH:11][CH:10]=1)(=[O:21])=[O:18]

Participants

4

Reactant 3

HCID 176Acetic AcidHCID 962WaterHCID 155519212-(Methylsulfanyl)-4'-nitro-1,1'-biphenyl

Product 1

HCID 15551922HCID 15551922, compound

Conditions

Temperature
60 °C

Procedure

A solution of 20.0 g (81.5 mmol) of 2-methylsulfanyl-4′-nitrobiphenyl in 150 ml of glacial acetic acid is treated with 66 g of sodium perborate trihydrate and heated at 60° C. with stirring for 3 days. The reaction mixture is added to water, and the precipitate is filtered off and recrystallized from petroleum ether/ethyl acetate. A yellowish solid is obtained; FAB 278

Workup

  1. filtrationthe precipitate is filtered off
  2. customrecrystallized from petroleum ether/ethyl acetate
  3. customA yellowish solid is obtained

Sources & evidence

ORD record
ord-c4ca4f7d78ae4781ae57542bc9c76682
Source dataset
uspto-grants-2005_09
Patent number
US06946489B2

Reaction notes

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