Furfural → HCID 66723099, compound

HRID 505708Notes

Reaction equation

HRID 505708 reaction equation
[CH3:1][O:2][C:3]([C:5]1[CH:14]=[CH:13][C:12]2[C:11](=[O:15])[CH2:10][CH2:9][CH2:8][C:7]=2[CH:6]=1)=[O:4].[O:16]1[CH:20]=[CH:19][CH:18]=[C:17]1[CH:21]=O>>[O:16]1[CH:20]=[CH:19][CH:18]=[C:17]1[CH:21]=[C:10]1[CH2:9][CH2:8][C:7]2[CH:6]=[C:5]([C:3]([O:2][CH3:1])=[O:4])[CH:14]=[CH:13][C:12]=2[C:11]1=[O:15]

Participants

3

Reactant 2

HCID 7362FurfuralHCID 15309116Methyl 5-oxo-5,6,7,8-tetrahydronaphthalene-2-carboxylate

Product 1

HCID 66723099HCID 66723099, compoundYield 80%

Procedure

The title compound was prepared from 5-oxo-5,6,7,8-tetrahydronaphtalene-2-carboxylic acid methyl ester (396 mg, 1.9 mmol) and 2-furaldehyde (192 mg, 2.0 mmol) according to Method A3 in 80% yield. ES-MS m/z 283 (M+H).

Sources & evidence

ORD record
ord-994e3fab3b014ecd8d367db8c14603d1
Source dataset
uspto-grants-2010_08
Patent number
US07781428B2

Reaction notes

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