Potassium Bicarbonate → HCID 178526056, compound

HRID 505972Notes

Reaction equation

HRID 505972 reaction equation
[F:1][S:2]([C:5]([C:8]([C:11]([O:14][C:15](C(F)=O)([C:17]([F:20])([F:19])[F:18])[F:16])([F:13])[F:12])([F:10])[F:9])([F:7])[F:6])(=[O:4])=[O:3].[C:24](=[O:27])(O)[O-:25].[K+:28]>C(COC)OC>[F:1][S:2]([C:5]([C:8]([C:11]([O:14][C:15]([C:24]([O:25][K:28])=[O:27])([C:17]([F:20])([F:19])[F:18])[F:16])([F:13])[F:12])([F:10])[F:9])([F:7])[F:6])(=[O:4])=[O:3]

Participants

4

Reactant 2

HCID 516893Potassium BicarbonateHCID 13530948HCID 13530948, compound

Product 1

HCID 178526056HCID 178526056, compound

Reagents, catalysts & solvents 1

HCID 80711,2-DimethoxyethaneSolvent

Procedure

FSO2(CF2)3OCF(CF3)COF is added dropwise to a flask under cooling with ice, into which potassium bicarbonate and monoglyme are charged, with stirring. After completion of the dropwise addition, stirring is continued further for 30 minutes, and then the solvent is distilled off. Vacuum drying is further carried out to obtain FSO2(CF2)3OCF(CF3)COOK.

Workup

  1. additionare charged
  2. additionAfter completion of the dropwise addition
  3. stirringstirring
  4. distillationthe solvent is distilled off
  5. customVacuum drying

Sources & evidence

ORD record
ord-f10354bd39e84bc5aeb03cfc0e8fa19b
Source dataset
uspto-grants-2010_08
Patent number
US07781612B2

Reaction notes

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