Ethanol → HCID 22737626, compound

HRID 51190Notes

Reaction equation

[CH2:1]([CH:4]1[CH2:9][CH2:8][CH:7]([SH:10])[CH2:6][CH2:5]1)[CH2:2][CH3:3].[OH-:11].[Na+].ClCCl.[CH2:16]([OH:18])C>>[CH2:1]([CH:4]1[CH2:9][CH2:8][CH:7]([S:10][O:11][CH2:16][O:18][S:10][CH:7]2[CH2:8][CH2:9][CH:4]([CH2:1][CH2:2][CH3:3])[CH2:5][CH2:6]2)[CH2:6][CH2:5]1)[CH2:2][CH3:3]

Participants

Reactant 4

HCID 702Ethanol

HCID 6344Dichloromethane

HCID 14798Sodium Hydroxide

HCID 227376604-Propylcyclohexane-1-thiol

Product 1

HCID 22737626HCID 22737626, compoundYield 103.9%

Procedure

Synthesis was conducted as in Synthesis Example 2 using 38.1 g (0.22 mol) of the 4-n-propylcyclohexylmercaptan prepared above, 9.4 g (0.23 mol) of sodium hydroxide, 77 g of ethanol and 14.3 g (0.17 mol) of dichloromethane. There was obtained 41.2 g of the desired formaldehyde bis(4-n-propylcyclohexylthio)acetal.

Workup

customSynthesis

Sources & evidence

ORD record: ord-5c52de48c65d4f0fa85cd406f282a05a
Source dataset: uspto-grants-2004_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06713612B2

Reaction notes

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