HCID 66931070, compound → HCID 66931303, compound

HRID 511959Notes

Reaction equation

HRID 511959 reaction equation
[CH3:1][O:2][C:3]1[CH:4]=[C:5]([CH:9]=[CH:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][O:16][C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=2)[CH:6]=[CH:7][CH:8]=1>[Pd].CCOC(C)=O>[CH3:1][O:2][C:3]1[CH:4]=[C:5]([CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][O:16][C:17]2[CH:18]=[CH:19][CH:20]=[CH:21][CH:22]=2)[CH:6]=[CH:7][CH:8]=1

Participants

4

Reactant 1

HCID 66931070HCID 66931070, compound

Product 1

HCID 66931303HCID 66931303, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 8857Ethyl AcetateSolvent

Procedure

1-(3-Methoxyphenyl)-7-phenoxy-heptane (8.2) was synthesized as described in 8.1 using 7.2 (0.55 g, 1.86 mmol), AcOEt (20 mL), and 10% Pd/C (0.080 g, 15% w/w). The title compound (8.2) was isolated as a colorless viscous liquid (0.53 g, 0.96% yield).

Workup

  1. custom1-(3-Methoxyphenyl)-7-phenoxy-heptane (8.2) was synthesized

Sources & evidence

ORD record
ord-ea527e7d44d847eb8f04dbf980a5124f
Source dataset
uspto-grants-2015_08
Patent number
US09102622B2

Reaction notes

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