Ethanol → HCID 71512042, compound

HRID 511968Notes

Reaction equation

HRID 511968 reaction equation
Br[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][C:9]1[CH:14]=[CH:13][CH:12]=[C:11]([O:15][CH2:16][C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=2)[CH:10]=1.[O-:23][S:24]([O-:26])=[O:25].[Na+:27].[Na+].CCO>O>[Na+:27].[CH2:16]([O:15][C:11]1[CH:10]=[C:9]([CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][S:24]([O-:26])(=[O:25])=[O:23])[CH:14]=[CH:13][CH:12]=1)[C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1

Participants

5

Reactant 3

HCID 702EthanolHCID 24437Sodium SulfiteHCID 66930962HCID 66930962, compound

Product 1

HCID 71512042HCID 71512042, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Following the procedure described for 11.1 using 10.2 (0.4 g, 1.1 mmol), Na2SO3 (0.19 g, 1.5 mmol) and EtOH (8 mL)/H2O (4 ml) mixture, the crude 11.2 was obtained and used in the next step without further purification.

Workup

  1. customthe crude 11.2 was obtained
  2. customused in the next step without further purification

Sources & evidence

ORD record
ord-d7d48d60812d4267960238516c788e38
Source dataset
uspto-grants-2015_08
Patent number
US09102622B2

Reaction notes

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