Ethanol → HCID 71512044, compound

HRID 511969Notes

Reaction equation

HRID 511969 reaction equation
Br[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=1[O:15][CH2:16][C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1.[O-:23][S:24]([O-:26])=[O:25].[Na+:27].[Na+].CCO>O>[Na+:27].[CH2:16]([O:15][C:10]1[CH:11]=[CH:12][CH:13]=[CH:14][C:9]=1[CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][S:24]([O-:26])(=[O:25])=[O:23])[C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1

Participants

5

Reactant 3

HCID 702EthanolHCID 24437Sodium SulfiteHCID 66931045HCID 66931045, compound

Product 1

HCID 71512044HCID 71512044, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Following the procedure described for 11.1 using 10.3 (0.231 g, 0.64 mmol), Na2SO3 (0.11 g, 0.89 mmol) and EtOH (8 mL)/H2O (4 ml) mixture, the crude 11.3 was obtained and used in the next step without further purification.

Workup

  1. customthe crude 11.3 was obtained
  2. customused in the next step without further purification

Sources & evidence

ORD record
ord-d5f17b3b7139468b8a863c011fa8cc2d
Source dataset
uspto-grants-2015_08
Patent number
US09102622B2

Reaction notes

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