Ethanol → HCID 71512046, compound

HRID 511970Notes

Reaction equation

HRID 511970 reaction equation
Br[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][C:7]1[CH:12]=[CH:11][C:10]([O:13][CH2:14][C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)=[CH:9][CH:8]=1.[O-:21][S:22]([O-:24])=[O:23].[Na+:25].[Na+].CCO>O>[Na+:25].[CH2:14]([O:13][C:10]1[CH:11]=[CH:12][C:7]([CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][S:22]([O-:24])(=[O:23])=[O:21])=[CH:8][CH:9]=1)[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1

Participants

5

Reactant 3

HCID 702EthanolHCID 24437Sodium SulfiteHCID 66931052HCID 66931052, compound

Product 1

HCID 71512046HCID 71512046, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Following the procedure described for 11.1 using 10.4 (0.95 g, 2.85 mmol), Na2SO3 (0.50 g, 4.0 mmol) and EtOH (25 mL)/H2O (7 ml) mixture, the crude 11.4 was obtained and used in the next step without further purification.

Workup

  1. customthe crude 11.4 was obtained
  2. customused in the next step without further purification

Sources & evidence

ORD record
ord-ceea3a33bed940bca6b10c13ded301b7
Source dataset
uspto-grants-2015_08
Patent number
US09102622B2

Reaction notes

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