Dipentylamine → HCID 178446346, compound

HRID 512100Notes

Reaction equation

HRID 512100 reaction equation
[CH2:1]([NH:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:2][CH2:3][CH2:4][CH3:5].[Br-].[Br:13][C:14]1[CH:15]=[CH:16][C:17]2[C:26]([CH:27]=1)=[S+:25][C:24]1[C:19](=[CH:20][CH:21]=[C:22](Br)[CH:23]=1)[N:18]=2>C(Cl)(Cl)Cl>[Br-:13].[CH2:7]([N:6]([CH2:1][CH2:2][CH2:3][CH2:4][CH3:5])[C:14]1[CH:15]=[CH:16][C:17]2[C:26]([CH:27]=1)=[S+:25][C:24]1[C:19](=[CH:20][CH:21]=[C:22]([N:6]([CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:1][CH2:2][CH2:3][CH2:4][CH3:5])[CH:23]=1)[N:18]=2)[CH2:8][CH2:9][CH2:10][CH3:11]

Participants

4

Reactant 2

HCID 16316DipentylamineHCID 162132753,7-Dibromophenothiazin-5-ium bromide

Product 1

HCID 178446346HCID 178446346, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

To a solution of 3.2 g (20.1 mmol) of dipentylamine in 60 mL of CHCl3 was added 4.37 g (10.03 mmol) of 22. The reaction mixture was stirred at r.t for 2 h under argon and concentrated under reduced pressure to give 3,7-bis(dipentylamino)phenothiazin-5-ium bromide (CPD-15): mass spectrum (MALDI-TOF), m/z 509.38 (M+H)+.

Workup

  1. concentrationconcentrated under reduced pressure

Sources & evidence

ORD record
ord-5c258c93932e499893b1c7d966ec23a7
Source dataset
uspto-grants-2015_08
Patent number
US09102626B2

Reaction notes

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