Water → HCID 86624088, compound

HRID 512465Notes

Reaction equation

HRID 512465 reaction equation
[F:1][C:2]([F:13])([C:9]([F:12])([F:11])[F:10])[C:3]([F:8])([F:7])[C:4](Cl)=[O:5].N1C=CC=CC=1.[CH:20]([O:22][CH2:23][CH2:24][CH2:25][CH3:26])=[CH2:21].O>ClCCl>[CH2:23]([O:22][CH:20]=[CH:21][C:4](=[O:5])[C:3]([F:8])([F:7])[C:2]([F:13])([F:1])[C:9]([F:12])([F:11])[F:10])[CH2:24][CH2:25][CH3:26]

Participants

6

Reactant 4

HCID 962WaterHCID 1049PyridineHCID 8108Butyl vinyl etherHCID 67810Heptafluorobutyryl Chloride

Product 1

HCID 86624088HCID 86624088, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent2×

Conditions

Temperature
-10 °C

Procedure

With stirring and at −10° C., 21.7 g (93.2 mmol) of heptafluorobutyryl chloride—dissolved in 50 ml of dichloromethane—were added to a mixture of 8.11 g (102 mmol) of pyridine and 9.33 g (93.2 mmol) of butyl vinyl ether in 200 ml of dichloromethane. After the addition, stirring was continued at room temperature for another 15 h. 300 ml of water were then added to the mixture, and the organic phase was separated off, dried and concentrated.

Workup

  1. additionAfter the addition
  2. stirringstirring
  3. customthe organic phase was separated off
  4. customdried
  5. concentrationconcentrated

Sources & evidence

ORD record
ord-fbfb89652cbe48b490778639a2f99daa
Source dataset
uspto-grants-2015_08
Patent number
US09102623B2

Reaction notes

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