Diethyl Ether → Silver isobutyrylacetate

HRID 522242Notes

Reaction equation

HRID 522242 reaction equation
N(CCO)CCO.CCOCC.[C:13]([CH2:18][C:19]([OH:21])=[O:20])(=[O:17])[CH:14]([CH3:16])[CH3:15].[N+]([O-])([O-])=O.[Ag+:26]>O>[C:13]([CH2:18][C:19]([O-:21])=[O:20])(=[O:17])[CH:14]([CH3:16])[CH3:15].[Ag+:26]

Participants

6

Reactant 4

HCID 3283Diethyl EtherHCID 8113DiethanolamineHCID 24470Silver NitrateHCID 4400244-Methyl-3-oxopentanoic acid

Product 1

HCID 86633510Silver isobutyrylacetate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Conditions

Temperature
15 °C

Procedure

Diethanolamine (0.33 g) was dissolved in water (5 ml) and an ether solution (10 ml) containing the isobutyrylacetic acid (0.43 g) was added thereto. Next, while stirring the obtained mixture at 15° C., an aqueous solution (5 ml) containing silver nitrate (0.51 g) was added dropwise thereto and further stirred for 15 minutes. The precipitated white precipitate was filtered out, thereby obtaining silver isobutyrylacetate (yield: 0.37 g).

Workup

  1. additionwas added
  2. additionwas added dropwise
  3. stirringfurther stirred for 15 minutes
  4. filtrationThe precipitated white precipitate was filtered out

Sources & evidence

ORD record
ord-e2060289d04048dd9bf1027b7f211717
Source dataset
uspto-grants-2016_05
Patent number
US09328254B2

Reaction notes

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