HRID522460

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID7187

Benzoyl peroxide

C14H10O4

HCID7636

2-Ethylhexyl acrylate

C11H20O2

HCID8906

Dodecyl 2-methylacrylate

C16H30O2

HCID12713

2-Ethylhexyl 2-methyl-2-propenoate

C12H22O2

PRODUCTS

生成物

结构：C=C(C)C(=O)OCC(CC)CCCC.C=C(C)C(=O)OCCCCCCCCCCCC.C=CC(=O)OCC(CC)CCCC

HCID86729957

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID8078

Cyclohexane

C6H12

溶剂HCID8857

Ethyl acetate

C4H8O2

2 次

CONDITIONS

反应条件

温度: 80 °C

PROCEDURE

实验过程

An acrylic adhesive A was prepared in the following manner. A reaction liquid containing monomers including 13 parts by weight of dodecyl methacrylate, 78 parts by weight of 2-ethylhexyl methacrylate, and 9 parts by weight of 2-ethylhexyl acrylate, and 50 parts by weight of ethyl acetate was supplied to a 40-L polymerization apparatus. Subsequently, a nitrogen atmosphere at 80° C. was maintained in the polymerization apparatus. To the reaction liquid, a polymerization initiator solution prepared by dissolving 0.5 parts by weight of benzoyl peroxide in 50 parts by weight of cyclohexane was added over 24 hours to copolymerize the above monomers. After the completion of the polymerization, ethyl acetate was further added to the reaction liquid to obtain an acrylic adhesive solution A containing 35% by weight of the acrylic adhesive A including a dodecyl methacrylate/2-ethylhexyl methacrylate/2-ethylhexyl acrylate copolymer.

WORKUP

后处理

customAn acrylic adhesive A was prepared in the following manner
customA reaction liquid
additioncontaining monomers
customTo the reaction liquid
customa polymerization initiator solution prepared
additionwas added over 24 hours to copolymerize the above monomers
additionwas further added to the reaction liquid

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-10134d1523fc427c880519c5679af08d
来源数据集: uspto-grants-2016_05
DOI: 10.6084/m9.figshare.5104873.v1
专利: US09333182B2
来源说明: uspto-grants-2016_05

反应 SMILES

[C:1]([O:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:19]([O:24][CH2:25][CH:26]([CH2:31][CH3:32])[CH2:27][CH2:28][CH2:29][CH3:30])(=[O:23])[C:20]([CH3:22])=[CH2:21].[C:33]([O:37][CH2:38][CH:39]([CH2:44][CH3:45])[CH2:40][CH2:41][CH2:42][CH3:43])(=[O:36])[CH:34]=[CH2:35].C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C1CCCCC1.C(OCC)(=O)C>[C:1]([O:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:19]([O:24][CH2:25][CH:26]([CH2:31][CH3:32])[CH2:27][CH2:28][CH2:29][CH3:30])(=[O:23])[C:20]([CH3:22])=[CH2:21].[C:33]([O:37][CH2:38][CH:39]([CH2:44][CH3:45])[CH2:40][CH2:41][CH2:42][CH3:43])(=[O:36])[CH:34]=[CH2:35]