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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 527852Generated: October 31, 2026

m-Chloroperbenzoic acid → 2-Methyl-propane-2-sulfonic acid (2-bromo-ethyl)-amide

https://huagongshe.com/reaction/527852

Reaction equation

Participants

RoleNameHCIDCharge
Reactantm-Chloroperbenzoic acidHCID 70297—
Reactant2-Methyl-propane-2-sulfinic acid (2-bromo-ethyl)-amideHCID 86713731—
Product2-Methyl-propane-2-sulfonic acid (2-bromo-ethyl)-amideHCID 6368880546.8%

Reaction Conditions

Temperature25 °C

Reaction Steps

To a solution of 2-methyl-propane-2-sulfinic acid (2-bromo-ethyl)-amide (0.8 g, 3.5 mmol) was added mCPBA (77%, 0.95 g, 4.2 mmol) and stirred at a temperature of about 25° C. for 2 hrs. The reaction mixture was condensed and purified to provide 2-methyl-propane-2-sulfonic acid (2-bromo-ethyl)-amide as a white solid (0.4 g, 46% yield).

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS09346808B2
Source datasetuspto-grants-2016_05
ORD IDord-9955dfe097094ee2be6631161f9d01e9
Source noteuspto-grants-2016_05