Caprolactam → HCID 86710476, compound

HRID 531427Notes

Reaction equation

HRID 531427 reaction equation
Cl[Pd:2]Cl.[OH-].[Na+].[C:6]1(=[O:13])[NH:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7]1>>[Pd:2].[C:6]1(=[O:13])[NH:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7]1

Participants

4

Reactant 3

HCID 7768Caprolactam2×HCID 14798Sodium HydroxideHCID 24290Palladium Chloride2×

Product 1

HCID 86710476HCID 86710476, compound

Conditions

Temperature
100 °C

Procedure

5.0 g PdCl2 and 100 g molten caprolactam having a purity not less than 80% and a moisture not more than 20% are added to a reactor, and then stirred for 30 min at the temperature of 100° C., so that PdCl2 is fully dissolved in a molten caprolactam solvent. 1 g NaOH is rapidly added under stirring for the purpose of reaction for 2 h at the temperature of 100° C., and then, 2 g KBH4 is added for continuous reaction for 2 h to obtain nano Pd/caprolactam mixture.

Workup

  1. additiona moisture not more than 20% are added to a reactor

Sources & evidence

ORD record
ord-cfad22c8bdd345e88282666a49c23a4e
Source dataset
uspto-grants-2016_05
Patent number
US09355765B2

Reaction notes

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