HRID53393

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CCSC1=CCC(C)(C)c2ccc(C#Cc3ccc(C(=O)O)cc3)cc21

HCID19962312

未命名化合物

2 次

结构：CCS(=O)(=O)C1=CCC(C)(C)c2cc(C#Cc3ccc(C(=O)O)cc3)ccc21

HCID19962323

未命名化合物

2 次

PRODUCTS

生成物

结构：CCS(=O)(=O)C1=CCC(C)(C)c2ccc(C#Cc3ccc(C(=O)O)cc3)cc21

HCID19962318

未命名化合物

PROCEDURE

实验过程

Employing the same general procedure as for the preparation of 4- (7,8-dihydro-8,8-dimethyl-5-ethylsulfonylnaphth-2-ylethynyl)benzoic acid (Compound 150), 25 mg (0.07 mmol) of 4-[(7,8-dihydro-8,8-dimethyl-5-ethylthionaphth-3-yl)ethynyl]benzoic acid (Compound 152) was converted to the title compound (white solid, recrystallized from ethyl alcohol) using 95 mg (0.28 mmol) of 50% 3-chloroperoxybenzoic acid.