Hydrochloric Acid → Ammonium trifluoromethanesulfonate

4.92 g of phenyltrimethoxysilane, 72.42 g of tetraethoxysilane, 22.05 g of methyltriethoxysilane, 0.61 g of the 30% methanol solution of trimethoxysilylpropyltrimethylammonium trifluoromethanesulfonate, and 150 g of acetone were charged into a 500 mL flask to be dissolved and the resultant mixed solution was warmed while stirring the mixed solution with a magnetic stirrer to reflux. Next, 33.11 g of 0.01 M hydrochloric acid was added to the mixed solution. The mixed solution was subjected to the reaction for 240 minutes and then the resultant reaction solution was cooled down to room temperature. Then, 200 g of propylene glycol monoethyl ether was added to the reaction solution, and ethanol and methanol as reaction by-products, acetone, water, and hydrochloric acid were distilled off under reduced pressure to obtain a hydrolysis-condensation product. The polymer thus obtained corresponded to Formula (VII-30):

1. dissolutionto be dissolved
2. additionthe resultant mixed solution
3. temperaturewas warmed
4. temperatureto reflux
5. customThe mixed solution was subjected to the reaction for 240 minutes
6. customthe resultant reaction solution
7. distillationwere distilled off under reduced pressure
8. customto obtain a hydrolysis-condensation product
9. customThe polymer thus obtained

ORD record

ord-ce4b5603365f4492aa4085411388b524

Source dataset

uspto-grants-2014_10

DOI

10.6084/m9.figshare.5104873.v1

Patent number

US08864894B2