Methyl Methacrylate → HCID 20319915, compound

HRID 539430Notes

Reaction equation

HRID 539430 reaction equation
[C:1]([O:6][CH3:7])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:8]([O:13][C:14]([CH3:17])([CH3:16])[CH3:15])(=[O:12])[C:9]([CH3:11])=[CH2:10]>>[C:1]([O:6][CH3:7])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:8]([O:13][C:14]([CH3:17])([CH3:16])[CH3:15])(=[O:12])[C:9]([CH3:11])=[CH2:10]

Participants

3

Reactant 2

HCID 6658Methyl Methacrylate2×HCID 11448tert-Butyl methacrylate

Product 1

HCID 20319915HCID 20319915, compound

Procedure

Similar operations as in Example 1 were carried out except that 0.13 g (1.3 mmols) of methyl methacrylate was changed to 0.10 g (1.0 mmols) of methyl methacrylate and 0.036 g (0.25 mmols) of tert-butyl methacrylate, thereby obtaining 0.28 g (yield ratio: 19%) of BHFC/methyl methacrylate/tert-butyl methacrylate copolymer (molar ratios=56:32:12). The weight average molecular weight Mw, determined by GPC, and 1H NMR of the thus obtained polymer are indicated below.

Workup

  1. customobtaining

Sources & evidence

ORD record
ord-f27364c2a3da4080ae42126fabcb212f
Source dataset
uspto-grants-2014_10
Patent number
US08871332B2

Reaction notes

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