Methanesulfonyl chloride → 2-Azidohexyl methanesulfonate

HRID 539533Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 539533
[N:1]([CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]CO)=[N+:2]=[N-:3].S(Cl)(C)(=O)=O.[CH3:16][S:17]([O:20][CH2:21]CN=[N+]=[N-])(=[O:19])=[O:18]>>[CH3:16][S:17]([O:20][CH2:21][CH:4]([N:1]=[N+:2]=[N-:3])[CH2:5][CH2:6][CH2:7][CH3:8])(=[O:19])=[O:18]

Komponenten

4

Edukt 3

HCID 31297Methanesulfonyl chlorideHCID 110517786-Azidohexan-1-olHCID 112751972-Azidoethyl methanesulfonate

Produkt 1

HCID 866750862-Azidohexyl methanesulfonate

Versuchsvorschrift

Reaction of 6-azidohexanol (0.74 g, 5.22 mmol) and mesyl chloride (0.61 mL, 7.83 mmol) within 3 h as described for synthesis of 156a gave compound 156e (0.87 g) as a crude colorless oil.

Quellen und Nachweise

ORD-Eintrag
ord-5508053fd4ec4bc5b6392bb3726e35a9
Quelldatensatz
uspto-grants-2014_10
Patentnummer
US08871728B2

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