Isoquinoline → Decahydroisoquinoline

HRID 542253Notes

Reaction equation

HRID 542253 reaction equation
[CH:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][N:2]=1>[Ru]>[CH2:1]1[CH:10]2[CH:5]([CH2:6][CH2:7][CH2:8][CH2:9]2)[CH2:4][CH2:3][NH:2]1

Participants

3

Reactant 1

HCID 8405Isoquinoline2×

Product 1

HCID 97812Decahydroisoquinoline

Reagents, catalysts & solvents 1

HCID 23950RutheniumCatalyst

Procedure

In this invention, when synthetic isoquinoline or refined coal tar isoquinoline or partially hydrogenated isoquinoline is used as the raw material, it is hydrogenated in its unmodified form in the presence of a ruthenium catalyst to produce decahydroisoquinoline.

Sources & evidence

ORD record
ord-0aaf7d2a5f544e0bb17984b6cbb8a3c0
Source dataset
uspto-grants-1987_04
Patent number
US04656279

Reaction notes

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