HCID 13931210, compound → HCID 14324147, compound

HRID 543091Notes

Reaction equation

HRID 543091 reaction equation
[F:1][C:2]([F:8])([F:7])[S:3]([O-:6])(=[O:5])=[O:4].[CH3:9][O:10][C:11]1[C:12](OC)=[CH:13][C:14]2[Te:18][C:17]([CH3:19])=[N+:16]([CH2:20][C:21]#[CH:22])[C:15]=2[CH:23]=1.COC1C=CC2[Te]C(C)=NC=2C=1>>[F:1][C:2]([F:8])([F:7])[S:3]([O-:6])(=[O:5])=[O:4].[CH3:9][O:10][C:11]1[CH:12]=[CH:13][C:14]2[Te:18][C:17]([CH3:19])=[N+:16]([CH2:20][C:21]#[CH:22])[C:15]=2[CH:23]=1

Participants

3

Reactant 2

HCID 13931210HCID 13931210, compoundHCID 144534255,6-Dimethoxy-2-methyl-3-(2-propyn-1-yl)benzotellurazolium Trifluoromethanesulfonate

Product 1

HCID 14324147HCID 14324147, compound

Procedure

This compound was prepared in the same way and on the same scale as the compound of Example 46, except that 5-methoxy-2-methylbenzotellurazole (Example 20) was used in place of the 5,6-dimethoxy-2-methylbenzotellurazole. Yield 1.23 g, 80% of theory, pale tan powder, m.p. 172°-174° C. (dec). The infrared, nuclear magnetic resonance, and mass spectra were in agreement with that expected for the structural formula.

Sources & evidence

ORD record
ord-e590e2049cb14a67af53b59b411d852e
Source dataset
uspto-grants-1987_04
Patent number
US04661438

Reaction notes

Loading…