Ethanol → HCID 86741448, compound

HRID 543101Notes

Reaction equation

HRID 543101 reaction equation
[P:1]([O-:6])([O:4]C)[O:2]C.O.[CH2:8](O)C.[CH3:11][O:12][CH2:13][CH2:14][CH2:15][NH2:16]>CO>[CH3:8][P:1](=[O:6])([O-:4])[O-:2].[CH3:11][O:12][CH2:13][CH2:14][CH2:15][NH3+:16].[CH3:11][O:12][CH2:13][CH2:14][CH2:15][NH3+:16]

Participants

6

Reactant 4

HCID 702EthanolHCID 962WaterHCID 16723-MethoxypropylamineHCID 21884954Dimethylphosphite

Product 1

HCID 86741448HCID 86741448, compoundYield 99.9%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

A mixture of 11 g. (0.1 moles) of dimethyl phosphite, 20 ml. of water and 20 ml. of ethanol is reacted with a mixture of 8.51 g. (0.1 moles) of 3-methoxypropyl amine and 30 ml. of methanol as described in Example 1. 18.5 g. of 3-methoxypropyl-ammoniummethyl phosphonate are obtained. Yield: 99.9%. nD30 =1.4449.

Workup

  1. additionA mixture of 11 g

Sources & evidence

ORD record
ord-3f867465b6544f8b89de31fb49cce87c
Source dataset
uspto-grants-1987_04
Patent number
US04661477

Reaction notes

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