Water → HCID 86741449, compound

HRID 543102Notes

Reaction equation

HRID 543102 reaction equation
[P:1]([O-])([O:4]C)[O:2][CH3:3].O.[CH2:8]([O:12][CH2:13][CH2:14][CH2:15][NH2:16])[CH2:9][CH2:10][CH3:11]>CO>[CH3:3][O:2][P:1]=[O:4].[CH2:8]([O:12][CH2:13][CH2:14][CH2:15][NH3+:16])[CH2:9][CH2:10][CH3:11]

Participants

5

Reactant 3

HCID 962WaterHCID 854611-Propanamine, 3-butoxy-HCID 21884954Dimethylphosphite

Product 1

HCID 86741449HCID 86741449, compoundYield 89.4%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent2×

Procedure

A mixture of 11 g. (0.1 moles) of dimethyl phosphite, 20 ml. of water and 20 ml. of methanol is reacted with a mixture of 13.12 g. (0.1 moles) of 3-butyloxypropyl amine and 30 ml. of methanol as described in Example 1. 22.6 g. of 3-butyloxypropyl-ammoniummethyl phosphanate are obtained. Yield: 89.4%. nD30 =1.4420

Workup

  1. additionA mixture of 11 g

Sources & evidence

ORD record
ord-0c69878de7dc4bf88cc335566ea05459
Source dataset
uspto-grants-1987_04
Patent number
US04661477

Reaction notes

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