Water → HCID 86741451, compound

HRID 543104Notes

Reaction equation

HRID 543104 reaction equation
[P:1]([O-])([O:5]CC)[O:2][CH2:3][CH3:4].O.[CH3:10][O:11][CH2:12][CH2:13][CH2:14][NH2:15]>C(O)C>[CH2:3]([O:2][P:1]=[O:5])[CH3:4].[CH3:10][O:11][CH2:12][CH2:13][CH2:14][NH3+:15]

Participants

5

Reactant 3

HCID 962WaterHCID 16723-MethoxypropylamineHCID 3780918Diethylphosphite

Product 1

HCID 86741451HCID 86741451, compoundYield 94.3%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent2×

Procedure

A mixture of 13.81 g. of diethyl phosphite, 20 ml. of water and 20 ml. of ethanol is reacted with a mixture of 8.91 g. (0.1 moles) of 3-methoxypropyl amine and 30 ml. of ethanol as described in Example 1. 18.8 g. of 3-methoxypropyl-ammoniumethyl phosphanate are obtained. Yield: 94.3%. nD30 =1,4440

Workup

  1. additionA mixture of 13.81 g

Sources & evidence

ORD record
ord-2d6af96cda8844c4b79ed0ef028deb87
Source dataset
uspto-grants-1987_04
Patent number
US04661477

Reaction notes

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