Hexamethylenetetramine → HCID 13423724, compound

HRID 543379Notes

Reaction equation

HRID 543379 reaction equation
Cl.N[CH2:3][C:4]1[CH:9]=[C:8]([CH:10]([CH3:12])[CH3:11])[CH:7]=[C:6]([S:13]([CH3:16])(=[O:15])=[O:14])[C:5]=1[OH:17].C1N2CN3CN(C2)CN1C3.FC(F)(F)C(O)=[O:31]>>[CH:3]([C:4]1[CH:9]=[C:8]([CH:10]([CH3:12])[CH3:11])[CH:7]=[C:6]([S:13]([CH3:16])(=[O:15])=[O:14])[C:5]=1[OH:17])=[O:31]

Participants

4

Reactant 3

HCID 4101HexamethylenetetramineHCID 6422Trifluoroacetic acidHCID 13210268HCID 13210268, compound

Product 1

HCID 13423724HCID 13423724, compound

Procedure

0.7 g (0.0025 mol) of 2-aminomethyl-4-isopropyl-6-methylsulfonylphenol hydrochloride are reacted with 0.45 g of urotropine in 8 ml of trifluoroacetic acid to give 2-formyl-4-isopropyl-6-methylsulfonylphenol in analogy to Example 1.

Sources & evidence

ORD record
ord-3c5c6aacebb549039bded6d33f330c87
Source dataset
uspto-grants-1987_04
Patent number
US04661636

Reaction notes

Loading…