Hexamethylenetetramine → HCID 20206368, compound

HRID 543381Notes

Reaction equation

HRID 543381 reaction equation
Cl.N[CH2:3][C:4]1[CH:9]=[C:8]([Cl:10])[CH:7]=[C:6]([S:11]([CH3:14])(=[O:13])=[O:12])[C:5]=1[OH:15].C1N2CN3CN(C2)CN1C3.FC(F)(F)C(O)=[O:29]>>[CH:3]([C:4]1[CH:9]=[C:8]([Cl:10])[CH:7]=[C:6]([S:11]([CH3:14])(=[O:13])=[O:12])[C:5]=1[OH:15])=[O:29]

Participants

4

Reactant 3

HCID 4101HexamethylenetetramineHCID 6422Trifluoroacetic acidHCID 13423718HCID 13423718, compound

Product 1

HCID 20206368HCID 20206368, compound

Procedure

2.4 g (0.009 mol) of 2-aminomethyl-4-chloro-6methylsulfonylphenol hydrochloride are reacted with 1.6 g of urotropine in 18 ml of trifluoroacetic acid to give 2-formyl-4-chloro-6-methylsulfonylphenol in analogy to Example 1.

Sources & evidence

ORD record
ord-fcbe5e80cbe542c8845d14534cced6f8
Source dataset
uspto-grants-1987_04
Patent number
US04661636

Reaction notes

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