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HRID543457

反应详情

EQUATION

反应方程式

HRID 543457 的结构方程式

REACTANTS

反应物

3
结构：C=C(C)C(=O)OCCO
HCID13360

2-Hydroxyethyl methacrylate

C6H10O3

结构：O=S(=O)([O-])OOS(=O)(=O)[O-].[NH4+].[NH4+]
HCID62648

Diammonium peroxydisulfate

H8N2O8S2

结构：C=C(C)P(=O)(O)O
HCID557541

Isopropenylphosphonic acid

C3H7O3P

PRODUCTS

生成物

1
结构：C=C(C)C(=O)OCCO.C=C(C)P(=O)(O)O
HCID86739386

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：O
溶剂HCID962

Water

H2O

PROCEDURE

实验过程

Aqueous isopropenyl phosphonic acid (71 g, 54%, 0.3 mole) and hydroxyethylmethacrylate (13 g, 0.1 mole) were mixed with 121.6 g water in a resin kettle. Ammonium persulfate (6 g) was added. After 11/2 hours of reflux, an additional 6 g of initiator was added followed by another 11/2 hours of reflux. The final product was a yellow solution with a pH of 0.68. The 31PMR showed polymeric absorptions centered at δ=-29.5 and -24.3 ppm.

WORKUP

后处理

  1. temperatureAfter 11/2 hours of reflux
  2. custom2 hours
  3. temperatureof reflux