HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Bromoanisole → 3-Bromoanisole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Bromoanisole | HCID 7730 | — |
| Reactant | 3-Bromophenol | HCID 11563 | — |
| Reactant | HCID 178506046 | HCID 178506046 | — |
| Product | 3-Bromoanisole | HCID 16971 | 40% |
Reaction Steps
2.9 mmol of parabromo-anisole and 15 cm3 of 1.7 M HF--SbF5 superacid are contacted for 55 hours at ambient temperature in a poly(tetrafluoroethylene) container. Chromatographic analysis of the reaction products shows that a mixture of meta-bromo-phenol (25%) and meta-bromoanisole (40%) is formed, in a 65% yield.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04447660 |
| Source dataset | uspto-grants-1984_05 |
| ORD ID | ord-92f2a33246254553a8d63aebdf918127 |
| Source note | uspto-grants-1984_05 |