Diphenylphosphine → HCID 14007796, compound

HRID 544512Notes

Reaction equation

HRID 544512 reaction equation
[CH:1]([Si:3]([CH2:10][CH2:11][CH3:12])([CH2:7][CH2:8][CH3:9])[CH2:4][CH2:5][CH3:6])=[CH2:2].[C:13]1([PH:19][C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1>>[CH2:10]([Si:3]([CH2:1][CH2:2][P:19]([C:20]1[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=1)[C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)([CH2:7][CH2:8][CH3:9])[CH2:4][CH2:5][CH3:6])[CH2:11][CH3:12]

Participants

3

Reactant 2

HCID 70017DiphenylphosphineHCID 13431037Ethenyl(tripropyl)silane

Product 1

HCID 14007796HCID 14007796, compound

Procedure

The vinyl tripropyl silane was then reacted with diphenyl phosphine with u.v. initiation for 86 hours in a manner described in the previous example. The conversion was about 95%. The mixture was fractionally distilled to yield the pure product as a clear, colorless, mobile liquid (see Table I).

Workup

  1. customfor 86 hours
  2. distillationThe mixture was fractionally distilled
  3. customto yield the pure product as a clear, colorless, mobile liquid (see Table I)

Sources & evidence

ORD record
ord-c9e7f5196c3c4fa48b5309be7da169a1
Source dataset
uspto-grants-1984_05
Patent number
US04450299

Reaction notes

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