Acrylic Acid → Zirconium(4+) tetraprop-2-enoate

HRID 550049Notes

Reaction equation

HRID 550049 reaction equation
C([O-])CCC.C([O-])CCC.C([O-])CCC.C([O-])CCC.[Zr+4:21].C(OCCOCCO)CCC.COC1C=CC(O)=CC=1.[C:42]([OH:46])(=[O:45])[CH:43]=[CH2:44]>C(O)CCC>[C:42]([O-:46])(=[O:45])[CH:43]=[CH2:44].[C:42]([O-:46])(=[O:45])[CH:43]=[CH2:44].[C:42]([O-:46])(=[O:45])[CH:43]=[CH2:44].[C:42]([O-:46])(=[O:45])[CH:43]=[CH2:44].[Zr+4:21]

Participants

6

Reactant 4

HCID 6581Acrylic AcidHCID 8177Diethylene Glycol Monobutyl EtherHCID 90154-MethoxyphenolHCID 160560Zirconium butoxide

Product 1

HCID 14497031Zirconium(4+) tetraprop-2-enoate

Reagents, catalysts & solvents 1

HCID 2631-ButanolSolvent

Conditions

Temperature
45 °C

Procedure

Into the flask described hereinabove there were placed 509.3 g of zirconium tetrabutanolate, 498.6 g of diethylene glycol monobutyl ether, and 2.8 g of 4-methoxyphenol. To this mixture there were quickly added in drops using a dropping funnel 382.7 grams of acrylic acid. The temperature thereby increased to 45° C. The product remained liquid and stable so that it could be heated to 90° C. during 30 minutes. The co-product butanol was expelled during 1 hour using vacuum up to 200 mbar.

Workup

  1. additionTo this mixture there were quickly added in drops
  2. temperaturestable so that it could be heated to 90° C. during 30 minutes

Sources & evidence

ORD record
ord-2ed1598de8544613ba84c917ac8e4c2a
Source dataset
uspto-grants-2011_05
Patent number
US07943798B2

Reaction notes

Loading…