Acrylic Acid → Magnesium acrylate

HRID 550050Notes

Reaction equation

HRID 550050 reaction equation
C([O-])CCC.C([O-])CCC.[Mg+2:11].C(OCCOCCO)CCC.COC1C=CC(O)=CC=1.[C:32]([OH:36])(=[O:35])[CH:33]=[CH2:34]>C(O)CCC>[C:32]([O-:36])(=[O:35])[CH:33]=[CH2:34].[C:32]([O-:36])(=[O:35])[CH:33]=[CH2:34].[Mg+2:11]

Participants

6

Reactant 4

HCID 6581Acrylic AcidHCID 8177Diethylene Glycol Monobutyl EtherHCID 90154-MethoxyphenolHCID 1674941-Butanol, magnesium salt (2:1)

Product 1

HCID 165336Magnesium acrylate

Reagents, catalysts & solvents 1

HCID 2631-ButanolSolvent

Conditions

Temperature
48 °C

Procedure

Into the flask described hereinabove there were placed 510.55 g of magnesium dibutanolate, 498.6 g of diethylene glycol monobutyl ether, and 2.8 g of 4-methoxyphenol. To this mixture there were quickly added in drops 431.7 grams of acrylic acid by means of a dropping funnel. The temperature thereby increased to 48° C. The product remained liquid and stable so that it could be heated to 90° C. during 30 minutes. The co-product butanol was expelled during 1 hour using vacuum up to 200 mbar.

Workup

  1. temperaturestable so that it could be heated to 90° C. during 30 minutes

Sources & evidence

ORD record
ord-a503a7ba559d44b2ad0960b0c165e18c
Source dataset
uspto-grants-2011_05
Patent number
US07943798B2

Reaction notes

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