Hydrazine hydrate (1:1) → 2,2-Dimethyl-4-pentenohydrazide

Participants

Role	Name	HCID	Charge
Reactant	Hydrazine hydrate (1:1)	HCID 24654	—
Reactant	Methyl 2,2-dimethylpent-4-enoate	HCID 11768679	—
Solvent	Methanol	HCID 887	—
Product	2,2-Dimethyl-4-pentenohydrazide	HCID 57691852	—

Reaction Conditions

Temperature	60 °C

Reaction Steps

To a solution of methyl 2,2-dimethyl-4-pentenoate (1 g) in MeOH (2 ml) was added hydrazine monohydrate (2.7 ml). The solution was heated in a close microwave vial at 60° C. for 12 h. Volatiles were evaporated in vacuo to give 1 g of the title compound as a yellow pale foam, which was used without further purification.

Provenance & Evidence

DOI	10.6084/m9.figshare.5104873.v1
Patent number	US07947683B2
Source dataset	uspto-grants-2011_05
ORD ID	ord-6389608f00bc4024aa9b779acd323f32
Source note	uspto-grants-2011_05