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HRID55558

反应详情

EQUATION

反应方程式

HRID 55558 的结构方程式

REACTANTS

反应物

3
结构：[BH4-].[Li+]
HCID4148881

Lithium borohydride

BH4Li

结构：CC(C)(C)OC(=O)N[C@@H](CCC(=O)O)C(=O)OC(C)(C)C
HCID6993444

Boc-Glu-OtBu

C14H25NO6

结构：CC(C)(C)OC(=O)[C@H](CCC(=O)O)NC(=O)OCc1ccccc1
HCID6994036

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)(C)OC(=O)CCC(CO)NC(=O)OC(C)(C)C
HCID4055117

未命名化合物

PROCEDURE

实验过程

Cbz-Glu-OtBu 51 is converted to 52 via the methyl ester followed by LiBH4 reduction according to the procedure of Y. Hamada, M. Shibata, T. Sugiura, S. Kato and T. Shioiri, J. Org. Chem.52:1242, 1987 used for the conversion of t-Boc-Glu-OtBu to the corresponding alcohol.