Phenylhydrazine → HCID 46193501, compound

HRID 555650Notes

Reaction equation

HRID 555650 reaction equation
[Se:1]1[CH:5]=[CH:4][CH:3]=[C:2]1[C:6]([C:8]1[CH:13]=[CH:12][C:11]([C:14]([O:16][CH3:17])=[O:15])=[CH:10][CH:9]=1)=O.[C:18]1([NH:24][NH2:25])[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1.C(N1C2C=C[Se]C=2C(C2OC(C(OC)=O)=CC=2)=N1)C1C=CC=CC=1>C(O)(=O)C>[C:18]1([N:24]2[C:3]3[CH:4]=[CH:5][Se:1][C:2]=3[C:6]([C:8]3[CH:13]=[CH:12][C:11]([C:14]([O:16][CH3:17])=[O:15])=[CH:10][CH:9]=3)=[N:25]2)[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1

Participants

5

Reactant 3

HCID 7516PhenylhydrazineHCID 46193254p-Methoxycarbonylphenyl 2-selenophenyl ketoneHCID 46193500HCID 46193500, compound

Product 1

HCID 46193501HCID 46193501, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

Compound 63 (5.86 g, 0.02 mole), phenylhydrazine 8 (4.36 g, 0.04 mole) and glacial acetic acid (1.5 ml) were allowed to react as in the preparation of compound 55 to afford compound 66. Yield: 1.93 g (25.3%); white crystals;

Sources & evidence

ORD record
ord-e215dd4c287f48ea8c414debe9532e62
Source dataset
uspto-grants-2011_11
Patent number
US08053459B1

Reaction notes

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