(Phenylmethyl)hydrazine → HCID 46193502, compound

HRID 555651Notes

Reaction equation

HRID 555651 reaction equation
[Se:1]1[CH:5]=[CH:4][CH:3]=[C:2]1[C:6]([C:8]1[CH:13]=[CH:12][C:11]([C:14]([O:16][CH3:17])=[O:15])=[CH:10][CH:9]=1)=O.[CH2:18]([NH:25][NH2:26])[C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1.C(N1C2C=C[Se]C=2C(C2OC(C(OC)=O)=CC=2)=N1)C1C=CC=CC=1>C(O)(=O)C>[CH2:18]([N:25]1[C:3]2[CH:4]=[CH:5][Se:1][C:2]=2[C:6]([C:8]2[CH:13]=[CH:12][C:11]([C:14]([O:16][CH3:17])=[O:15])=[CH:10][CH:9]=2)=[N:26]1)[C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1

Participants

5

Reactant 3

HCID 11157(Phenylmethyl)hydrazineHCID 46193254p-Methoxycarbonylphenyl 2-selenophenyl ketoneHCID 46193500HCID 46193500, compound

Product 1

HCID 46193502HCID 46193502, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

Compound 63 (5.86 g, 0.02 mole), benzylhydrazine 50 (4.88 g, 0.04 mole) and glacial acetic acid (1.5 ml) were allowed to react as in the preparation of compound 55 to afford compound 67. Yield: 2.49 g (31.4%); white crystals; mp 150-153° C.

Sources & evidence

ORD record
ord-4156d3071a3343a18d49e066173fd7b5
Source dataset
uspto-grants-2011_11
Patent number
US08053459B1

Reaction notes

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