Water → HCID 66765778, compound

HRID 556778Notes

Reaction equation

HRID 556778 reaction equation
[CH3:1][O:2][C:3]1[CH:8]=[C:7]([O:9][CH3:10])[CH:6]=[CH:5][C:4]=1[C@@H:11]1[O:19][C@H:18]([CH2:20][OH:21])[C@@H:16]([OH:17])[C@H:14]([OH:15])[C@H:12]1[OH:13].[C:22](Cl)(=[O:27])[C:23]([CH3:26])([CH3:25])[CH3:24].[OH2:29]>N1C=CC=CC=1>[C:22]([O:13][C@@H:12]1[C@@H:14]([O:15][C:22](=[O:29])[C:23]([CH3:26])([CH3:25])[CH3:24])[C@H:16]([O:17][C:22](=[O:27])[C:23]([CH3:26])([CH3:25])[CH3:24])[C@@H:18]([CH2:20][O:21][C:22](=[O:27])[C:23]([CH3:26])([CH3:25])[CH3:24])[O:19][C@H:11]1[C:4]1[CH:5]=[CH:6][C:7]([O:9][CH3:10])=[CH:8][C:3]=1[O:2][CH3:1])(=[O:27])[C:23]([CH3:26])([CH3:25])[CH3:24]

Participants

5

Reactant 3

HCID 962WaterHCID 62493Pivaloyl chlorideHCID 66765802HCID 66765802, compound

Product 1

HCID 66765778HCID 66765778, compound

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

To a solution of 1-deoxy-1-(2,4-dimethoxyphenyl)-β-D-glucopyranose (0.47 g) in pyridine (10 mL) was added pivaloyl chloride (1.1 g) at room temperature, and the mixture was stirred at room temperature overnight. The reaction mixture was poured into water, and the mixture was extracted with diethyl ether.

Workup

  1. extractionthe mixture was extracted with diethyl ether

Sources & evidence

ORD record
ord-3a1d304941af4e2099980beb59e46fa0
Source dataset
uspto-grants-2011_11
Patent number
US08058245B2

Reaction notes

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