Cinnamoylbenzene → HCID 86752921, compound

HRID 564668Notes

Reaction equation

HRID 564668 reaction equation
C1([NH:7][NH2:8])C=CC=CC=1.[C:9]1([CH:15]=[CH:16][C:17]([C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=2)=O)[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1>C(O)C>[C:9]1([CH:15]=[CH:16][C:17](=[N:7][NH2:8])[C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=2)[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1

Participants

4

Reactant 2

HCID 7189CinnamoylbenzeneHCID 7516Phenylhydrazine

Product 1

HCID 86752921HCID 86752921, compoundYield 125.2%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

Another colorant stabilizer of the present invention is a basic fuschin hydrazone, prepared as follows. To a 500 ml round bottom flask, fitted with a magnetic stirrer and a heating mantle, was placed 50 g (0.46 mole) phenyl hydrazine (Aldrich), 96.3 g (0.46 mole) chalcone (Aldrich), and 300 ml. of anhydrous ethanol. The reaction mixture refluxed overnight and then cooled to room temperature. A white precipitate formed and was filtered to yield a white solid which was washed with cold ether. 128 g (93%) chalcone hydrazone was obtained. This reaction is shown below.

Workup

  1. customprepared
  2. customTo a 500 ml round bottom flask, fitted with a magnetic stirrer
  3. temperatureThe reaction mixture refluxed overnight
  4. customA white precipitate formed
  5. filtrationwas filtered
  6. customto yield a white solid which
  7. washwas washed with cold ether

Sources & evidence

ORD record
ord-f148f8c1cb044cf58fc89b62ba2f7dbc
Source dataset
uspto-grants-2001_01
Patent number
US06168655A

Reaction notes

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