2-Octanone → tert-Butyl N'-(1-methyl-heptylidene)-hydrazinecarboxylate

HRID 566318Notes

Reaction equation

HRID 566318 reaction equation
[CH3:1][C:2](=O)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[C:10]([O:14][C:15]([CH3:18])([CH3:17])[CH3:16])(=[O:13])[NH:11][NH2:12]>C1CCCCC1>[CH3:1][C:2](=[N:12][NH:11][C:10]([O:14][C:15]([CH3:18])([CH3:17])[CH3:16])=[O:13])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

Participants

4

Reactant 2

HCID 80932-OctanoneHCID 70091tert-Butyl carbazate

Product 1

HCID 72599198tert-Butyl N'-(1-methyl-heptylidene)-hydrazinecarboxylate

Reagents, catalysts & solvents 1

HCID 8078CyclohexaneSolvent

Procedure

40 g (312 mmol) of 2-octanone and 41.23 g (312 mmol) of tert-butyl carbazate are refluxed for 2 hours in 350 ml of cyclohexane. The solvent and water are removed in vacuo. This gives 74.10 g (98%) of a waxy solid.

Workup

  1. customThe solvent and water are removed in vacuo

Sources & evidence

ORD record
ord-e0b12e0f9acd4b18a123b7e768916f98
Source dataset
uspto-grants-2001_01
Patent number
US06174884B1

Reaction notes

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