Benzoyl Peroxide → 1,1'-(3-Bromoprop-1-ene-1,1-diyl)dibenzene

HRID 566536Notes

Reaction equation

HRID 566536 reaction equation
[C:1]1([C:7]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)=[CH:8][CH3:9])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.[Br:34]N1C(=O)CCC1=O>C(Cl)(Cl)(Cl)Cl>[Br:34][CH2:9][CH:8]=[C:7]([C:10]1[CH:11]=[CH:12][CH:13]=[CH:14][CH:15]=1)[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 2382071,1-Diphenyl-1-propene

Product 1

HCID 123465451,1'-(3-Bromoprop-1-ene-1,1-diyl)dibenzene

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

A mixture of 1,1-diphenyl-1-propene (17.0 g, 0.10 mol), carbontetrachloride (100 ml), benzoylperoxide (0.2 g) and N-bromosuccinimide (17.8 g, 0.10 mol) was heated at reflux temperature for 18 h. The reaction mixture was allowed to cool to room temperature, filtered and the solvent was evaporated in vacuo to give 3-bromo-1, 1-diphenyl-1-propene in a quantitative yield.

Workup

  1. temperaturewas heated
  2. temperatureat reflux temperature for 18 h
  3. filtrationfiltered
  4. customthe solvent was evaporated in vacuo

Sources & evidence

ORD record
ord-af3f193276504907b8aa0a030f1ba784
Source dataset
uspto-grants-2001_01
Patent number
US06174898B1

Reaction notes

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