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HRID567391

反应详情

EQUATION

反应方程式

HRID 567391 的结构方程式

REACTANTS

反应物

4
结构：[K+].[OH-]
HCID14797

Potassium hydroxide

HKO

结构：C=CC(C)(O)/C=C/C1=C(C)CCCC1(C)C
HCID6436846

(1E)-3-Methyl-1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,4-pentadien-3-ol

C15H24O

结构：Cl.c1ccc(P(c2ccccc2)c2ccccc2)cc1
HCID12196763

未命名化合物

结构：C=C1C=CC[C@@H](C)[C@@]1(C)CCC1=CC(O)OC1=O
HCID21773091

未命名化合物

PRODUCTS

生成物

1
结构：CC1=C(/C=C/C(C)=C/C=C/C(C)=C\C(=O)O)C(C)(C)CCC1
HCID5282379

13-cis Retinoic acid

C20H28O2

AUXILIARIES

试剂、催化剂与溶剂

2
结构：CCO
溶剂HCID702

Ethanol

C2H6O

结构：O
溶剂HCID962

Water

H2O

PROCEDURE

实验过程

43 g of the mixture of retinoic acids from the condensation of hydroxy butenolide, vinyl beta-ionol and triphenylphosphine hydrochloride in 10 ml of ethanol are treated with 15 g of a 50% potassium hydroxide aqueous solution, subsequently diluted to 200 mL with water, added with 30 mg of Bengal rose, then irradiated with a 18 Watt lamp for 12 hours.

WORKUP

后处理

  1. additionadded with 30 mg of Bengal
  2. customirradiated with a 18 Watt lamp for 12 hours