化工社化工社 化学情報印刷レポート · 研究参考用
Peracetic Acid → Peracetic Acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Peracetic Acid | HCID 6585 | — |
| 反応物 | Codeinone | HCID 5459910 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | Peracetic Acid | HCID 6585 | — |
| 生成物 | (4R,4aS,12bS)-4a-hydroxy-9-methoxy-3-methyl-2,4,7a,13-tetrahydro-1H-4,12-methanobenzofuro[3,2-e]isoquinolin-7-one | HCID 5359420 | — |
反応手順
14-Hydroxycodeinone was synthesized from the dienolsilyl ether of codeinone by oxidative hydroxylation using a peracetic acid solution preparation. The peracetic acid solution was prepared as follows:
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06177567B1 |
| 出典データセット | uspto-grants-2001_01 |
| ORD ID | ord-380c0706ce624b569b2a107fe5673d80 |
| 出典メモ | uspto-grants-2001_01 |