HRID567428

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6585

Peracetic acid

C2H4O3

结构：COc1ccc2c3c1O[C@H]1C(=O)C=C[C@H]4[C@@H](C2)N(C)CC[C@]314

HCID5459910

Codeinone

C18H19NO3

PRODUCTS

生成物

HCID6585

Peracetic acid

C2H4O3

结构：COc1ccc2c3c1OC1C(=O)C=C[C@@]4(O)[C@@H](C2)N(C)CC[C@]314

HCID5359420

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID3283

Diethyl Ether

C4H10O

PROCEDURE

实验过程

14-Hydroxycodeinone was synthesized from the dienolsilyl ether of codeinone by oxidative hydroxylation using a peracetic acid solution preparation. The peracetic acid solution was prepared as follows: