HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium hydride → HCID 13315114, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium hydride | HCID 24758 | — |
| Reactant | HCID 13315113 | HCID 13315113 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 13315114 | HCID 13315114 | — |
Reaction Steps
270 mg of 6-benzyloxycarbonyl-3-methylsulfinyl-β-carboline are refluxed for 1.5 hours with an alcoholate solution prepared from 27 mg 80% sodium hydride and 15 ml of absolute ethanol. After concentration, it is picked up in ethyl acetate and suctioned off. 78 mg of 6-ethoxycarbonyl-3-methylsulfinyl-β-carboline with a 240°-243° C. melting point are obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04731358 |
| Source dataset | uspto-grants-1988_03 |
| ORD ID | ord-786aa1112cf9422889c5516c779b509f |
| Source note | uspto-grants-1988_03 |