HRID569547

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6409

2,2,2-Trifluoroethanol

C2H3F3O

$结构：CC1(C)[C@H](C(=O)OCc2ccccc2)[C@@H]1/C=C\C(=O)O$

HCID86740331

未命名化合物

PRODUCTS

生成物

$结构：CC1(C)[C@H](C(=O)OCc2ccccc2)[C@@H]1/C=C\C(=O)OCC(F)(F)F$

HCID13335667

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID6212

Chloroform

CHCl3

PROCEDURE

实验过程

Using the procedure of Example 53, trifluoroethanol and the product of Step B of Example 57 were reacted to obtain benzyl(1R,cis,Z)2,2-dimethyl-3-[3-oxo-3-(2,2,2-trifluoroethoxy)-1-propenyl]-cyclopropane-carboxylate with a specific rotation of [α]D20 =+45° (c=0.6% in chloroform).