Carbazole → HCID 57757333, compound

HRID 573395Notes

Reaction equation

HRID 573395 reaction equation
Br[C:2]1[CH:3]=[CH:4][C:5]2[N:6]([C:16]3[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=3)[C:7]3[C:12]([C:13]=2[CH:14]=1)=[CH:11][C:10](Br)=[CH:9][CH:8]=3.[CH:22]1[C:34]2[NH:33][C:32]3[C:27](=[CH:28][CH:29]=[CH:30][CH:31]=3)[C:26]=2[CH:25]=[CH:24][CH:23]=1.C(O[CH2:39][CH3:40])(=O)C>CCCCCC>[CH:4]1[C:5]2[N:6]([C:16]3[CH:21]=[CH:20][C:19]4[N:6]([C:40]5[CH:39]=[CH:12][CH:7]=[CH:8][CH:9]=5)[C:5]5[C:13]([C:18]=4[CH:17]=3)=[CH:14][C:2]([N:33]3[C:32]4[CH:31]=[CH:30][CH:29]=[CH:28][C:27]=4[C:26]4[C:34]3=[CH:22][CH:23]=[CH:24][CH:25]=4)=[CH:3][CH:4]=5)[C:7]3[C:12](=[CH:11][CH:10]=[CH:9][CH:8]=3)[C:13]=2[CH:14]=[CH:2][CH:3]=1

Participants

5

Reactant 3

HCID 6854CarbazoleHCID 8857Ethyl AcetateHCID 110257913,6-Dibromo-9-phenylcarbazole

Product 1

HCID 57757333HCID 57757333, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

The Rf values of the objective substance, 3,6-dibromo-9-phenyl-9H-carbazole, and carbazole were respectively 0.32, 0.73, and 0.18 which were obtained by silica gel thin layer chromatography (TLC) (with a developing solvent containing ethyl acetate and hexane in a 1:10 ratio).

Workup

  1. custom0.18 which were obtained by silica gel thin layer chromatography (TLC) (with a developing solvent

Sources & evidence

ORD record
ord-ad2ff312ee554e73a2411b0cc173eee6
Source dataset
uspto-grants-2015_05
Patent number
US09029558B2

Reaction notes

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