huagongshe.com
HRID575237

反应详情

EQUATION

反应方程式

HRID 575237 的结构方程式

REACTANTS

反应物

3
结构：CC(C)(C)[Si](C)(C)O[Si](C)(C)C(C)(C)C
HCID590018

TBDMS ether

C12H30OSi2

结构：NC(=O)c1cn2c(n1)-c1cc(Br)ccc1OCC2
HCID68312883

未命名化合物

结构：C#CC(C)(C)CO[Si](C)(C)C(C)(C)C
HCID86669580

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)(C#Cc1ccc2c(c1)-c1nc(C(N)=O)cn1CCO2)CO
HCID71715454

未命名化合物

收率 28%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CC#N
溶剂HCID6342

Acetonitrile

C2H3N

PROCEDURE

实验过程

Similar to as described in General Procedure G, 10-bromo-5,6-dihydrobenzo[f]imidazo[1,2-d][1,4]oxazepine-2-carboxamide was reacted with tert-butyl[(2,2-dimethylbut-3-yn-1-yl)oxy]dimethylsilane to give the titled compound as a off-white solid (35 mg, 28%) after deprotection of the tert-butyldimethylsilyl ether (HF/MeCN).